Just had a chat with someone on-line about a scripted install, as of ESX 3.5 the way to enable VMotion via the command-line changed. So for anyone looking for this particular command:
/usr/bin/vmware-vim-cmd "hostsvc/vmotion/vnic_set vmk0"
In this example “vmk0” is the first vmkernel. This is one of the things that changed, so no portgroup id’s anymore. And if you need to do anything via the command-line that doesn’t seem to be possible with the normal commands: vmware-vim-cmd. Definitely the way to go.