I was able to connect my PowerCLI instance without any problems to my vCenter, until all of a sudden I got the following error:

Connect-VIServer : 8/12/2010 11:51:36 Connect-VIServer
Could not connect using the requested protocol.

I discovered that this was due to a change in the Proxy Server settings on the client. After removing this proxy address everything was back to normal.

-ray